Please use this identifier to cite or link to this item: https://scholar.ptuk.edu.ps/handle/123456789/179
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dc.contributor.authorShahin, Nabil
dc.contributor.authorAbu-Khalaf, Nawaf
dc.contributor.authorSalman, Mazen
dc.contributor.authorParlar, Harun
dc.date.accessioned2018-12-16T09:35:13Z
dc.date.available2018-12-16T09:35:13Z
dc.date.issued2016-12
dc.identifier.citationShahin, Nabil; et.al.(2016). "Testing the Possibility of Photochemical Synthesis of Chlorinated Phenols, Benzenes and Biphenyl: Pre-study Guide for Standards Synthesis". Palestine Technical University Research Journal: 4(2), 73-83. www.ptuk.edu.psen_US
dc.identifier.issn2307-809x
dc.identifier.urihttps://scholar.ptuk.edu.ps/handle/123456789/179
dc.description.abstractSince deuterium 2H (D) is an isotope of hydrogen 1H, the testing of the possibility of photochemical synthesis of marked chlorinated phenol, biphenyl and benzene using normal solvents was studied. The irradiation of full chlorinated compounds dissolved in normal solvents such as MeOH or n-hexane has led to a reaction substitution in which a chlorine atom was substituted by hydrogen atom forming less grade chlorinated chlorophenols, biphenyls and benzenes. The quantum yields of pentachlorophenol, decachlorobiphenyl and hexachlorobenzene under irradiation using polychromatic light were calculated and found to be 5.7 x 10-3, 1.6 x 10-2 and 1.2 x 10-2 Mol·Einstein-1, respectively. Depending on this study the production of marked chlorinated or non-chlorinated compounds using deuterated appropriate solvents such as MeOH d4 or n-hexane d14 is possible. However, more efforts should be made towards chromatographically separation of synthesized standards and byproducts in order to make the use of these marked compounds as standards in residue analysis feasible.en_US
dc.language.isoenen_US
dc.publisherPTUKen_US
dc.relation.ispartofseries4(2);73-83
dc.subjectmarked standards, polychromatic quantum yield, synthesis, photochemical, pentachlorophenol, decachlorobiphenyl, hexachlorobenze.en_US
dc.titleTesting the Possibility of Photochemical Synthesis of Chlorinated Phenols, Benzenes and Biphenyl: Pre-study Guide for Standards Synthesisen_US
dc.typeArticleen_US
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